«The photochemical determinants of color vision»: الفرق بين المراجعتين
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تعليق: من مقالة عام 1992: iminium ions of omeprazole + proton pumping in the vision. وهذه المقالة تقول أيضاً the Schiff base is protonated. Retinal bound to opsins as a '''protonated Schiff base PSB (an iminium)''' absorb at different wavelengths | تعليق: من مقالة عام 1992: iminium ions of omeprazole + proton pumping in the vision. وهذه المقالة تقول أيضاً the Schiff base is protonated. Retinal bound to opsins as a '''protonated Schiff base PSB (an iminium)''' absorb at different wavelengths | ||
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Retinal absorbs at 380 nm in ethanol and it blue shifts to 360 nm when it forms a Schiff base (an imine) with n-butylamine. A large red shift to 440 nm results when the Schiff base is protonated. Retinal bound to opsins as a '''PSB (an iminium)''' absorb at different wavelengths. The difference between the protein-bound PSB absorbance and 440 nm is referred to as the “opsin shift”, and represents the protein-induced change in absorption spectrum of the pigment as compared with that of the native protonated retinylidene Schiff base [41]. | Retinal absorbs at 380 nm in ethanol and it blue shifts to 360 nm when it forms a Schiff base (an imine) with n-butylamine. A large red shift to 440 nm results when the Schiff base is protonated. Retinal bound to opsins as a '''PSB (an iminium)''' absorb at different wavelengths. The difference between the protein-bound PSB absorbance and 440 nm is referred to as the “opsin shift”, and represents the protein-induced change in absorption spectrum of the pigment as compared with that of the native protonated retinylidene Schiff base [41]. | ||
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https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4104663/ | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4104663/ | ||
| − | [[تصنيف:Proton pump inhibitors in | + | [[تصنيف:Proton pump inhibitors in retina]] |
المراجعة الحالية بتاريخ 15:39، 3 نوفمبر 2016
تعليق: من مقالة عام 1992: iminium ions of omeprazole + proton pumping in the vision. وهذه المقالة تقول أيضاً the Schiff base is protonated. Retinal bound to opsins as a protonated Schiff base PSB (an iminium) absorb at different wavelengths
Retinal absorbs at 380 nm in ethanol and it blue shifts to 360 nm when it forms a Schiff base (an imine) with n-butylamine. A large red shift to 440 nm results when the Schiff base is protonated. Retinal bound to opsins as a PSB (an iminium) absorb at different wavelengths. The difference between the protein-bound PSB absorbance and 440 nm is referred to as the “opsin shift”, and represents the protein-induced change in absorption spectrum of the pigment as compared with that of the native protonated retinylidene Schiff base [41].
